{"id":13864,"date":"2021-01-27T10:04:20","date_gmt":"2021-01-27T02:04:20","guid":{"rendered":"http:\/\/www.ace-pow.com\/?p=13864"},"modified":"2024-02-21T11:50:29","modified_gmt":"2024-02-21T03:50:29","slug":"%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e6%ad%a3%e6%9e%81%e6%9d%90%e6%96%99%e7%9a%84%e4%bc%98%e7%bc%ba%e7%82%b9","status":"publish","type":"post","link":"http:\/\/www.ace-pow.com\/archives\/13864","title":{"rendered":"\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u4f18\u7f3a\u70b9"},"content":{"rendered":"\n<p style=\"font-size:16px\">\u9502\u79bb\u5b50\u7535\u6c60\u7684\u7279\u6027\u548c\u4ef7\u683c\u90fd\u4e0e\u5b83\u7684\u6b63\u6781\u6750\u6599\u5bc6\u5207\u76f8\u5173\uff0c\u4e00\u822c\u800c\u8a00\uff0c\u6b63\u6781\u6750\u6599\u5e94\u6ee1\u8db3\uff1a\uff081\uff09\u5728\u6240\u8981\u6c42\u7684\u5145\u653e\u7535\u7535\u4f4d\u8303\u56f4\u5185\uff0c\u5177\u6709\u4e0e\u7535\u89e3\u8d28\u6eb6\u6db2\u7684\u7535\u5316\u5b66\u76f8\u5bb9\u6027\uff1b\uff082\uff09\u6e29\u548c\u7684\u7535\u6781\u8fc7\u7a0b\u52a8\u529b\u5b66\uff1b\uff083\uff09\u9ad8\u5ea6\u53ef\u9006\u6027\uff1b\uff084\uff09\u5168\u9502\u72b6\u6001\u4e0b\u5728\u7a7a\u6c14\u4e2d\u7a33\u5b9a\u6027\u80fd\u597d\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter\"><img loading=\"lazy\" width=\"650\" height=\"403\" src=\"http:\/\/www.ace-pow.com\/wp-content\/uploads\/2021\/01\/569-2.jpg\" alt=\"\u9502\u79bb\u5b50\u7535\u6c60\" class=\"wp-image-13865\" srcset=\"http:\/\/www.ace-pow.com\/wp-content\/uploads\/2021\/01\/569-2.jpg 650w, http:\/\/www.ace-pow.com\/wp-content\/uploads\/2021\/01\/569-2-300x186.jpg 300w, http:\/\/www.ace-pow.com\/wp-content\/uploads\/2021\/01\/569-2-610x378.jpg 610w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/figure><\/div>\n\n\n<p style=\"font-size:16px\">\u968f\u7740\u9502\u79bb\u5b50\u7535\u6c60\u7684\u53d1\u5c55\uff0c\u9ad8\u6027\u80fd\u3001\u4f4e\u6210\u672c\u7684\u6b63\u6781\u6750\u6599\u7814\u7a76\u5de5\u4f5c\u5728\u4e0d\u65ad\u5730\u8fdb\u884c\u3002\u76ee\u524d\uff0c\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u4e8e\u9502\u94bb\u6c27\u5316\u7269\u3001\u9502\u954d\u6c27\u5316\u7269\u548c\u9502\u9530\u6c27\u5316\u7269\u7b49\u9502\u7684\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u3002<\/p>\n\n\n\n<p style=\"font-size:16px\">\u9502\u94bb\u6c27\u5316\u7269\uff08LiCo02\uff09\u5c5e\u4e8ea-NaFe02\u578b\u7ed3\u6784\uff0c\u5177\u6709\u4e8c\u7ef4\u5c42\u72b6\u7ed3\u6784\uff0c\u9002\u5b9c\u9502\u79bb\u5b50\u7684\u8131\u5d4c\u3002\u7531\u4e8e\u5176\u5236\u5907\u5de5\u827a\u8f83\u4e3a\u7b80\u4fbf\u3001\u6027\u80fd\u7a33\u5b9a\u3001\u6bd4\u5bb9\u91cf\u9ad8\u3001\u5faa\u73af\u6027\u80fd\u597d\uff0c\u76ee\u524d\u5546\u54c1\u5316\u7684\u9502\u79bb\u5b50\u7535\u6c60\u5927\u90fd\u91c7\u7528LiCo02\u4f5c\u4e3a\u6b63\u6781\u6750\u6599\u3002\u5176\u5408\u6210\u65b9\u6cd5\u4e3b\u8981\u6709\u9ad8\u6e29\u56fa\u76f8\u5408\u6210\u6cd5\u548c\u4f4e\u6e29\u56fa\u76f8\u5408\u6210\u6cd5\uff0c\u8fd8\u6709\u8349\u9178\u6c89\u6dc0\u6cd5\u3001\u6eb6\u80f6\u51dd\u80f6\u6cd5\u3001\u51b7\u70ed\u6cd5\u3001\u6709\u673a\u6df7\u5408\u6cd5\u7b49\u8f6f\u5316\u5b66\u65b9\u6cd5\u3002<\/p>\n\n\n\n<p style=\"font-size:16px\">\u9502\u954d\u6c27\u5316\u7269\uff08LiNi02\uff09\u4e3a\u5ca9\u76d0\u578b\u7ed3\u6784\u5316\u5408\u7269\uff0c\u5177\u6709\u826f\u597d\u7684\u9ad8\u6e29\u7a33\u5b9a\u6027\u3002\u7531\u4e8e\u81ea\u653e\u7535\u7387\u4f4e\u3001\u5bf9\u7535\u89e3\u6db2\u7684\u8981\u6c42\u4f4e\u3001\u4e0d\u6c61\u67d3\u73af\u5883\u3001\u8d44\u6e90\u76f8\u5bf9\u4e30\u5bcc\u4e14\u4ef7\u683c\u9002\u5b9c\uff0c\u662f\u4e00\u79cd\u5f88\u6709\u5e0c\u671b\u4ee3\u66ff\u9502\u94bb\u6c27\u5316\u7269\u7684\u6b63\u6781\u6750\u6599\u3002\u76ee\u524dLiNi02\u4e3b\u8981\u901a\u8fc7Ni\uff08NO3\uff092\u3001N i\uff08OH\uff092\u3001NiCO3\u3001NiOOH\u548cLiOH\u3001LiN03\u53caLiC03\u7ecf\u56fa\u76f8\u53cd\u5e94\u5408\u6210\u3002LiNi02\u7684\u5408\u6210\u6bd4LiCo02\u56f0\u96be\uff0c\u5176\u4e3b\u8981\u539f\u56e0\u662f\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u5316\u5b66\u8ba1\u91cf\u6bd4\u7684LiNi02\u5bb9\u6613\u5206\u89e3\u4e3aLi1-xNi1+x02\uff0c\u8fc7\u91cf\u7684\u954d\u79bb\u5b50\u5904\u4e8eNi02\u5e73\u9762\u4e4b\u95f4\u7684\u9502\u5c42\u4e2d\uff0c\u59a8\u788d\u4e86\u9502\u79bb\u5b50\u7684\u6269\u6563\uff0c\u5c06\u5f71\u54cd\u6750\u6599\u7684\u7535\u5316\u5b66\u6d3b\u6027\uff0c\u540c\u65f6\u7531\u4e8eNi3+\u6bd4Co3+\u96be\u5f97\u5230\uff0c\u56e0\u6b64\u7684\u5408\u6210\u5fc5\u987b\u5728\u6c27\u6c14\u6c14\u6c1b\u4e2d\u8fdb\u884c[2]<\/p>\n\n\n\n<p style=\"font-size:16px\">\u9502\u9530\u6c27\u5316\u7269\u662f\u4f20\u7edf\u6b63\u6781\u6750\u6599\u7684\u6539\u6027\u7269\uff0c\u76ee\u524d\u5e94\u7528\u8f83\u591a\u7684\u662f\u5c16\u6676\u77f3\u578bLixMn204\uff0c\u5b83\u5177\u6709\u4e09\u7ef4\u96a7\u9053\u7ed3\u6784\uff0c\u66f4\u9002\u5b9c\u9502\u79bb\u5b50\u7684\u8131\u5d4c\u3002\u9502\u9530\u6c27\u5316\u7269\u539f\u6599\u4e30\u5bcc\u3001\u6210\u672c\u4f4e\u5ec9\u3001\u65e0\u6c61\u67d3\u3001\u8010\u8fc7\u5145\u6027\u53ca\u70ed\u5b89\u5168\u6027\u66f4\u597d\uff0c\u5bf9\u7535\u6c60\u7684\u5b89\u5168\u4fdd\u62a4\u88c5\u7f6e\u8981\u6c42\u76f8\u5bf9\u8f83\u4f4e\uff0c\u88ab\u8ba4\u4e3a\u662f\u6700\u5177\u6709\u53d1\u5c55\u6f5c\u529b\u7684\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u3002Mn\u6eb6\u89e3\u3001Jahn-Telle\u6548\u5e94\u53ca\u7535\u89e3\u6db2\u7684\u5206\u89e3\u88ab\u8ba4\u4e3a\u662f\u5bfc\u81f4\u9502\u9530\u6c27\u5316\u7269\u4e3a\u6b63\u6781\u6750\u6599\u7684\u9502\u79bb\u5b50\u7535\u6c60\u5bb9\u91cf\u635f\u5931\u7684\u6700\u4e3b\u8981\u539f\u56e0\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u9502\u79bb\u5b50\u7535\u6c60\u7684\u7279\u6027\u548c\u4ef7\u683c\u90fd\u4e0e\u5b83\u7684\u6b63\u6781\u6750\u6599\u5bc6\u5207\u76f8\u5173\uff0c\u4e00\u822c\u800c\u8a00\uff0c\u6b63\u6781\u6750\u6599\u5e94\u6ee1\u8db3\uff1a\uff081\uff09\u5728\u6240\u8981\u6c42\u7684\u5145\u653e\u7535\u7535\u4f4d\u8303\u56f4\u5185\uff0c\u5177\u6709\u4e0e\u7535\u89e3\u8d28\u6eb6\u6db2\u7684\u7535\u5316\u5b66\u76f8\u5bb9\u6027\uff1b\uff082\uff09\u6e29\u548c\u7684\u7535\u6781\u8fc7\u7a0b\u52a8\u529b\u5b66\uff1b\uff083\uff09\u9ad8\u5ea6\u53ef\u9006\u6027\uff1b\uff084\uff09\u5168\u9502\u72b6\u6001\u4e0b\u5728\u7a7a\u6c14\u4e2d\u7a33\u5b9a\u6027\u80fd\u597d\u3002 \u968f\u7740\u9502\u79bb\u5b50\u7535\u6c60\u7684\u53d1\u5c55\uff0c\u9ad8\u6027\u80fd\u3001\u4f4e\u6210\u672c\u7684\u6b63\u6781\u6750\u6599\u7814\u7a76\u5de5\u4f5c\u5728\u4e0d\u65ad\u5730\u8fdb\u884c\u3002\u76ee\u524d\uff0c\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u4e8e\u9502\u94bb\u6c27\u5316\u7269\u3001\u9502\u954d\u6c27\u5316\u7269\u548c\u9502\u9530\u6c27\u5316\u7269\u7b49\u9502\u7684\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u3002 \u9502\u94bb\u6c27\u5316\u7269\uff08LiCo02\uff09\u5c5e\u4e8ea-NaFe02\u578b\u7ed3\u6784\uff0c\u5177\u6709\u4e8c\u7ef4\u5c42\u72b6\u7ed3\u6784\uff0c\u9002\u5b9c\u9502\u79bb\u5b50\u7684\u8131\u5d4c\u3002\u7531\u4e8e\u5176\u5236\u5907\u5de5\u827a\u8f83\u4e3a\u7b80\u4fbf\u3001\u6027\u80fd\u7a33\u5b9a\u3001\u6bd4\u5bb9\u91cf\u9ad8\u3001\u5faa\u73af\u6027\u80fd\u597d\uff0c\u76ee\u524d\u5546\u54c1\u5316\u7684\u9502\u79bb\u5b50\u7535\u6c60\u5927\u90fd\u91c7\u7528LiCo02\u4f5c\u4e3a\u6b63\u6781\u6750\u6599\u3002\u5176\u5408\u6210\u65b9\u6cd5\u4e3b\u8981\u6709\u9ad8\u6e29\u56fa\u76f8\u5408\u6210\u6cd5\u548c\u4f4e\u6e29\u56fa\u76f8\u5408\u6210\u6cd5\uff0c\u8fd8\u6709\u8349\u9178\u6c89\u6dc0\u6cd5\u3001\u6eb6\u80f6\u51dd\u80f6\u6cd5\u3001\u51b7\u70ed\u6cd5\u3001\u6709\u673a\u6df7\u5408\u6cd5\u7b49\u8f6f\u5316\u5b66\u65b9\u6cd5\u3002 \u9502\u954d\u6c27\u5316\u7269\uff08LiNi02\uff09\u4e3a\u5ca9\u76d0\u578b\u7ed3\u6784\u5316\u5408\u7269\uff0c\u5177\u6709\u826f\u597d\u7684\u9ad8\u6e29\u7a33\u5b9a\u6027\u3002\u7531\u4e8e\u81ea\u653e\u7535\u7387\u4f4e\u3001\u5bf9\u7535\u89e3\u6db2\u7684\u8981\u6c42\u4f4e\u3001\u4e0d\u6c61\u67d3\u73af\u5883\u3001\u8d44\u6e90\u76f8\u5bf9\u4e30\u5bcc\u4e14\u4ef7\u683c\u9002\u5b9c\uff0c\u662f\u4e00\u79cd\u5f88\u6709\u5e0c\u671b\u4ee3\u66ff\u9502\u94bb\u6c27\u5316\u7269\u7684\u6b63\u6781\u6750\u6599\u3002\u76ee\u524dLiNi02\u4e3b\u8981\u901a\u8fc7Ni\uff08NO3\uff092\u3001N i\uff08OH\uff092\u3001NiCO3\u3001NiOOH\u548cLiOH\u3001LiN03\u53caLiC03\u7ecf\u56fa\u76f8\u53cd\u5e94\u5408\u6210\u3002LiNi02\u7684\u5408\u6210\u6bd4LiCo02\u56f0\u96be\uff0c\u5176\u4e3b\u8981\u539f\u56e0\u662f\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u5316\u5b66\u8ba1\u91cf\u6bd4\u7684LiNi02\u5bb9\u6613\u5206\u89e3\u4e3aLi1-xNi1+x02\uff0c\u8fc7\u91cf\u7684\u954d\u79bb\u5b50\u5904\u4e8eNi02\u5e73\u9762\u4e4b\u95f4\u7684\u9502\u5c42\u4e2d\uff0c\u59a8\u788d\u4e86\u9502\u79bb\u5b50\u7684\u6269\u6563\uff0c\u5c06\u5f71\u54cd\u6750\u6599\u7684\u7535\u5316\u5b66\u6d3b\u6027\uff0c\u540c\u65f6\u7531\u4e8eNi3+\u6bd4Co3+\u96be\u5f97\u5230\uff0c\u56e0\u6b64\u7684\u5408\u6210\u5fc5\u987b\u5728\u6c27\u6c14\u6c14\u6c1b\u4e2d\u8fdb\u884c[2] \u9502\u9530\u6c27\u5316\u7269\u662f\u4f20\u7edf\u6b63\u6781\u6750\u6599\u7684\u6539\u6027\u7269\uff0c\u76ee\u524d\u5e94\u7528\u8f83\u591a\u7684\u662f\u5c16\u6676\u77f3\u578bLixMn204\uff0c\u5b83\u5177\u6709\u4e09\u7ef4\u96a7\u9053\u7ed3\u6784\uff0c\u66f4\u9002\u5b9c\u9502\u79bb\u5b50\u7684\u8131\u5d4c\u3002\u9502\u9530\u6c27\u5316\u7269\u539f [&hellip;]<\/p>\n","protected":false},"author":3720,"featured_media":13865,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[178],"tags":[534],"_links":{"self":[{"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/posts\/13864"}],"collection":[{"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/users\/3720"}],"replies":[{"embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/comments?post=13864"}],"version-history":[{"count":2,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/posts\/13864\/revisions"}],"predecessor-version":[{"id":18888,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/posts\/13864\/revisions\/18888"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/media\/13865"}],"wp:attachment":[{"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/media?parent=13864"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/categories?post=13864"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/tags?post=13864"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}